Synthesis, characterisation and anti-diabetic activities of triorganotin(IV) azo-carboxylates derived from amino benzoic acids and resorcinol: Crystal structure and topological study of a 48 membered macrocyclic-tetrameric trimethyltin(IV) complex
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- 作者：Manojit Roya ; Subhadip Roya ; Keisham Surjit Singha ; surjitkeisham@yahoo.co.in" class="auth_mail" title="E-mail the corresponding author ; singh1971@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Janmoni Kalitab ; S. Sureshkumar Singhb
- 关键词：Azo-carboxylates ; Triorganotin(IV) complexes ; NMR spectroscopy ; Macrocyclic tetramer ; Anti-diabetic activities
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：439
- 期：Complete
- 页码：164-172
- 全文大小：1599 K
文摘
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Triorganotin(IV) azo-carboxylates 1–5 derived from amino benzoic acids and resorcinol were synthesized and characterised.
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Structure of compound 3 was determined by X-ray crystallography and its topological analysis was carried out.
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3 is a 48 membered macrocylic tetrameric compound with trans-trigonal bipyramidal geometry around tin atoms.
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Complexes exhibit better anti-diabetic activities than the standard compound.