CO₂ sorption behavior of imidazole, benzimidazole and benzoic acid based coordination polymers

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• 作者：Rashmi A. Agarwal ; ^{rashmi.a.agarwal@gmail.com} ; Neeraj K. Gupta
• 关键词：Porous coordination polymers ; CO2 ; Sorption ; Imidazole ; Benzimidazole ; Benzoic acid
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：332
• 期：Complete
• 页码：100-121
• 全文大小：10721 K
• 卷排序：332

文摘

PCPs designed by utilizing imidazole/benzimidazole and benzoic acid based linkers. CO2 sorption influenced by strong non-covalent interactions. These interactions include π-π, anion-π, CH-π, and H-bondings. Interaction potentials decide selective sorption as function of temperature & pressure. PCPs have good commercial potential if utilized in membranes for CO2 capture.