Hydrothermal syntheses and structures of cobalt(II) and copper(II) coordination polymers with 1-tetrazole-phenyl-4-methylphosphonate ligands

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• 作者：Tiffany M. Smith Pellizzeri^a ; Y.-Z. Zhang^b ; Jonathan Gooch^a ; Adam Lau^a ; Sharde McLeish^a ; Kim R. Dunbar^b ; ^{Dunbar@mail.chem.tamu.edu} ; Jon Zubieta^a ; ^{jazubiet@syr.edu}
• 关键词：Solid state coordination chemistry ; Metal-organophosphonate ; Mixed tetrazole/phosphonic acid ligand ; cobalt(II)-tetrazole-phosphonate chain ; copper(II)-tetrazolate-phosphonate network
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 March 2017
• 年：2017
• 卷：458
• 期：Complete
• 页码：109-115
• 全文大小：1245 K
• 卷排序：458

文摘

Syntheses and structural characterizations of a mixed dipodal ligand, 1-tetrazole-phenyl-4-methyphosphonic acid. Hydrothermal synthesis of the two-dimensional Cu(II) phosphonate coordination polymer (1·H2O). Hydrothermal synthesis of the one-dimensional cobalt(II) analogue (2·2H2O). Correlation of structure with competing ferromagnetic coupling and antiferromagnetic coupling for (2·2H2O).