Hydrogen bonding induced UCST phase transition of poly(ionic liquid)-based nanogels
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- 作者：Yong Zuoa ; zuoyong_only@163.com" class="auth_mail" title="E-mail the corresponding author ; Zhenqian Jiaoa ; Li Maa ; Pengfei Songa ; Rongmin Wanga ; wangrmcn@163.com" class="auth_mail" title="E-mail the corresponding author ; Yubing Xionga ; b ; xiongyb@mpip-mainz.mpg.de" class="auth_mail" title="E-mail the corresponding author ; yubing_xiong@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ionic liquids ; Thermo-response ; Nanogel ; Cross-linking polymerization ; UCST
- 刊名：Polymer
- 出版年：2016
- 出版时间：19 August 2016
- 年：2016
- 卷：98
- 期：Complete
- 页码：287-293
- 全文大小：1270 K
文摘
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IL monomers with hydroxyl and carboxyl groups are prepared.
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Functional nanogels are obtained via one-step ternary copolymerization.
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PIL-based nanogels are thermoresponsive. • UCST of PIL-based nanogel can be tuned via the feed ratio.
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Reversible nanogel-macrogel transition can be achieved with high [VCMIm]Cl feed.