Cross relaxation in nitroxide spin labels

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作者：Derek Marsh ; ^{dmarsh@gwdg.de" class="auth_mail" title="E-mail the corresponding author}
关键词：Spin-lattice relaxation ; Saturation recovery ; Progressive saturation ; EPR ; ELDOR
刊名：Journal of Magnetic Resonance
出版年：2016
出版时间：November 2016
年：2016
卷：272
期：Complete
页码：172-180
全文大小：650 K

文摘

class="label">•: Spin-population rates for 14N-, 15N-nitroxides with cross relaxation & class="mathmlsrc">class="formulatext stixSupport mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si1.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=9279e81bd34e0cc3af1885231848f834" title="Click to view the MathML source">m_Iclass="mathContainer hidden">class="mathCode"> $<$ msub>mImsub>-dependent class="mathmlsrc">class="formulatext stixSupport mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si2.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=4865d0c7e1ee2dd978fdfb6d179003c7" title="Click to view the MathML source">T_1eclass="mathContainer hidden">class="mathCode"> $<$ msub>T1emsub>.
class="label">•: class="mathmlsrc">class="formulatext stixSupport mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si1.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=9279e81bd34e0cc3af1885231848f834" title="Click to view the MathML source">m_Iclass="mathContainer hidden">class="mathCode"> $<$ msub>mImsub>-independent saturation recovery rates arise naturally from population differences.
class="label">•: Saturation recovery gives mean class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si4.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=f02d1c6939324ee8c7ba76ec87999099">class="imgLazyJSB inlineImage" height="21" width="25" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S1090780716301847-si4.gif">class="mathContainer hidden">class="mathCode"> $<$ msubsup>T1e-1msubsup> & cross-relaxation rates, independent of pump & observer positions.
class="label">•: Cross relaxation exceeds class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si4.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=f02d1c6939324ee8c7ba76ec87999099">class="imgLazyJSB inlineImage" height="21" width="25" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S1090780716301847-si4.gif">class="mathContainer hidden">class="mathCode"> $<$ msubsup>T1e-1msubsup> electron-nuclear dipolar contribution to recovery rates.
class="label">•: Cross relaxation & class="mathmlsrc">class="formulatext stixSupport mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si1.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=9279e81bd34e0cc3af1885231848f834" title="Click to view the MathML source">m_Iclass="mathContainer hidden">class="mathCode"> $<$ msub>mImsub>-dependent class="mathmlsrc">class="formulatext stixSupport mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si2.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=4865d0c7e1ee2dd978fdfb6d179003c7" title="Click to view the MathML source">T_1eclass="mathContainer hidden">class="mathCode"> $<$ msub>T1emsub> contribute less than nuclear relaxation to class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S1090780716301847&_mathId=si8.gif&_user=111111111&_pii=S1090780716301847&_rdoc=1&_issn=10907807&md5=8bb6b7a8bc662456e4ef51ea98b75e97">class="imgLazyJSB inlineImage" height="21" width="25" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S1090780716301847-si8.gif">class="mathContainer hidden">class="mathCode"> $<$ msubsup>T1effmsubsup> in CW-EPR.

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