Investigations on the lability of CO in (NHC)Rh(CO)2Cl complexes
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- 作者：Hannes Buhl ; Christian Ganter ; christian.ganter@hhu.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：N-heterocyclic carbenes ; Rhodium complexes ; DMSO
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 May 2016
- 年：2016
- 卷：809
- 期：Complete
- 页码：74-78
- 全文大小：679 K
文摘
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CO exchanges reversibly for DMSO in complexes of the type (NHC)Rh(CO)2Cl.
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The substitution occurs readily at room temperature and is associative in nature.
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X-ray structures indicate that the CO ligand trans to the NHC is replaced.