A New Theory of Potential Step Chronoamperometry at Hemispheroidal Electrodes: Complete Explicit Semi-Analytical Formulae for the Faradaic Current Density and the Faradaic Current

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• 作者：L.K. Bieniasz¹ ; ^{nbbienia@cyf-kr.edu.pl}
• 关键词：hemispheroidal microelectrode ; chronoamperometry ; limiting current ; Laplace transformation ; spheroidal wave functions
• 刊名：Journal of Electroanalytical Chemistry
• 出版年：2017
• 出版时间：1 January 2017
• 年：2017
• 卷：784
• 期：Complete
• 页码：91-101
• 全文大小：1413 K
• 卷排序：784

文摘

New theory of chronoamperometry at hemispheroidal electrodes Valid for oblate and prolate hemispheroids under limiting current conditions Rigorous semi-analytical formulae for Faradaic current density and current Highly accurate current values from numerically inverted Laplace transforms Suitable for experimental data analysis and validation of modelling methods