Comprehensive monitoring of MEA degradation in a post-combustion CO2 capture pilot plant with identification of novel degradation products in gaseous effluents
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- 作者：Ludovic Chahena ; Thierry Huarda ; Lorena Cucciab ; Vincent Cuzuelb ; José ; Dugayb ; Valé ; rie Pichonb ; Jé ; rô ; me Vialb ; Camille Gouedarda ; Leslie Bonnarda ; Nadè ; ge Celliera ; Pierre-Louis Carrettea ; p-louis.carrette@ifpen.fr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ethanolamine degradation products in gas effluents ; Pilot plant monitoring ; Novel analytical methods ; Solid phase extraction ; Nitrosamines ; Stripper gas effluents analysis
- 刊名：International Journal of Greenhouse Gas Control
- 出版年：2016
- 出版时间：August 2016
- 年：2016
- 卷：51
- 期：Complete
- 页码：305-316
- 全文大小：1050 K
文摘
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A pilot plant campaign was performed to study MEA degradation.
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Specific methods were developed for sampling, sample conditioning and analysis.
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Developed gas phase sampling enabled identification of 17 novel degradation products.
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Several derivatives of pyrazine, pyridine and oxazolidine were identified.
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1H-pyrrole and a new nitrosamine, the N-nitroso-2-methyloxazolidine were identified.