The unexpected product of Diels-Alder reaction between “indanocyclon” and maleimide

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• 作者：Michał A. Dobrowolski^a ; ^{miked@chem.uw.edu.pl} ; Piotr Roszkowski^a ; Marta Struga^b ; Daniel Szulczyk^b
• 关键词：Indanocyclon ; Maleimide ; Diels-Alder ; X-ray diffraction
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：1130
• 期：Complete
• 页码：573-578
• 全文大小：962 K
• 卷排序：1130

文摘

Unexpected additional product of Diels-Alder reaction was isolated and characterized. Formation of the product relies on formation of unfavorable transition state in reaction between reactants. Single crystals of both products were isolated and extensively examined by X-Ray diffraction technique.