Binuclear organoplatinum(II) complexes with double bis(diphenylphosphino)acetylene bridges: Synthesis, X-ray structure determination, electronic structures and DFT calculations
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- 作者：S. Masoud Nabavizadeha ; nabavi@chem.susc.ac.ir" class="auth_mail" title="E-mail the corresponding author ; nabavizadeh@shirazu.ac.ir" class="auth_mail" title="E-mail the corresponding author ; Hajar Sepehrpoura ; Mahboubeh Jamshidia ; Fatemeh Niroomand Hosseinib ; Anita M. Owczarzakc ; Maciej Kubickic
- 关键词：Diphosphines ; Platinum ; Crystal structures ; DFT calculations ; Electronic structures
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 April 2016
- 年：2016
- 卷：808
- 期：Complete
- 页码：34-41
- 全文大小：2029 K
文摘
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New cyclometalated diplatinum(II) complexes are prepared.
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The structures of diplatinum(IV) complexes bridged by two dppac ligand are determined.
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The electronic structures of the complexes are theoretically studied.