Structural reinvestigation of Li3FeN2: Evidence of cationic disorder through XRD, solid-state NMR and Mössbauer spectroscopy
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- 作者：E. Panabiè ; rea ; N. Emerya ; emery@icmpe.cnrs.fr" class="auth_mail" title="E-mail the corresponding author ; C. Lorthioirb ; M.T. Sougratic ; J.-C. Jumasc ; S. Bacha ; d ; J.-P. Pereira-Ramosa ; R.I. Smithe ; P. Willmannf
- 关键词：Lithiated transition metal nitrides ; Cationic mixing
- 刊名：Journal of Physics and Chemistry of Solids
- 出版年：2016
- 出版时间：August 2016
- 年：2016
- 卷：95
- 期：Complete
- 页码：37-42
- 全文大小：2067 K
文摘
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Evidence of cationic disorder in Li3FeN2.
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Crystal structure refinement using powder X-ray diffraction (Rietveld refinement).
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Number and occupation of lithium environment probed by 6Li/7Li NMR.
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Iron environment and oxidation state analyzed by 57Fe Mössbauer spectroscopy.