Graphene wrapped LiMn0.5Fe0.5PO4 is synthesized using Li3PO4/graphene oxide.
The mechanism and composite structure evolution are investigated.
The LiMn0.5Fe0.5PO4 particles inherit the size of Li3PO4 nanoparticles.
The composite delivers capacity 101.3 mA h g−1 at 10 C.