Electrochemical promotion and characterization of PdZn alloy catalysts with K and Na ionic conductors for pure gaseous CO2 hydrogenation
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- 作者：J. Dí ; ez-Ramí ; rez ; Javier.Diez@uclm.es" class="auth_mail" title="E-mail the corresponding author ; javi74.dr@gmail.com" class="auth_mail" title="E-mail the corresponding author ; P. Sá ; nchez ; J.L. Valverde ; F. Dorado
- 关键词：Electrochemical promotion of catalysis (EPOC) ; CO2 hydrogenation ; PdZn alloy ; Methanol production
- 刊名：Journal of CO2 Utilization
- 出版年：2016
- 出版时间：December 2016
- 年：2016
- 卷：16
- 期：Complete
- 页码：375-383
- 全文大小：2713 K
文摘
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PdZn alloy was used for the first time as a catalytic electrochemical film.
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The PdZn alloy proved to be active for CO2 hydrogenation to give CO and CH3OH.
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The EPOC effect varies depending on the particles (metallic Pd or PdZn alloy).
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The apparent Faradaic efficiency for CO reached values higher than 1000.