Modeling of key reaction pathways: Zeolite catalyzed alkylation processes

详细信息    查看全文

• 作者：Subramanya V. Nayak ; Palghat A. Ramach ; ran ; Milorad P. Dudukovic
• 关键词：Isobutane/n-butene alkylation ; Zeolites ; Catalyst deactivation ; Kinetics ; Reactor-zeolite mathematical modeling
• 刊名：Chemical Engineering Science
• 出版年：2010
• 出版时间：1 January 2010
• 年：2010
• 卷：65
• 期：1
• 页码：335-342
• 全文大小：1105 K

文摘

A six lump kinetic model that considers the key reactions for the zeolite catalyzed alkylation process is presented. The influence of different reactions and rate limiting steps on reactor performance is examined by coupling an appropriate reactor model that accounts for different back-mixing on reactor scale, with a zeolite particle model which accounts for the diffusion inside the zeolite pore, the alkylation reaction, and zeolite deactivation. Model predictions are compared with experimental results and lead to conclusions that hydride transfer and oligomerization reactions are the key kinetic steps affecting the overall performance of zeolite catalyzed alkylation processes. It is suggested that higher alkylate yield and longer zeolite activity are achieved by increasing the intrinsic hydride transfer rate and the ratio of feed isobutane to n-butene (P/O) concentration. For a given P/O feed ratio, achieving close to plug flow for isobutane and high back-mixing for n-butene further enhances local P/O ratio and yield. Furthermore, optimal zeolite catalyst design should consider the egg shell type of Brønsted acid site distribution and a lower silicon to alumina (Si/Al) ratio.