A 3D Monte-Carlo Model is built to simulate photochemical escape from early Mars. ∼1 m GEL H2O and 20 mbar CO2 was lost through photochemical escape since 4.5 Ga. Contributions of 2ndary O and C can reach 40% and 8% of total escape at ∼4.1 Ga. O2+ and CO+ DR are the main sources of escaping O at 1–10 and 20 × XUV respectively. CO2+ and CO+ DR are the main sources of escaping C at 1 and 3–20 × XUV respectively.