CO hydrogenation reaction over FeCo catalyst; a micro-kinetic approach for studying the kinetics and mechanism of hydrocarbon formation

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• 作者：Mehdi Shiva^a ; Hossein Atashi^a ; ^{atashi_usb@yahoo.com} ; Farhad Farshchi Tabrizi^a ; Ali Akbar Mirzaei^b ; Maryam Arsalanfar^b
• 关键词：ASF ; Anderson&ndash ; Schulz&ndash ; Flory ; LHHW ; Langmuir&ndash ; Hinshelwood&ndash ; Hougen&ndash ; Watson ; MARI ; most abundant reactive intermediate ; RDS ; rate determining step ; UBI-QEP ; unity bond index quadratic exponential potential
• 刊名：Journal of Industrial and Engineering Chemistry
• 出版年：2013
• 出版时间：25 January, 2013
• 年：2013
• 卷：19
• 期：1
• 页码：172-181
• 全文大小：378 K

文摘

The study addresses an enhanced approach for study of kinetics and mechanism of CO hydrogenation over FeCo catalyst. Kinetic models for rate of methane, paraffin and olefin formation have been developed by LHHW approach and information that obtained from UBI_QEP calculations.