Chemical oxidation of ferrocenyl(phenyl)phosphines and ferrocenyl(phenyl)phosphine chalcogenides
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- 作者：Michael J. Verschoor-Kirssb ; 1 ; Olivia Hendricksc ; 2 ; Carla M. Verschoorc ; Rebecca Conryb ; Rein U. Kirssa ; r.kirss@neu.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ferrocene ; Phosphine ; Electrochemistry ; Oxidation
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 August 2016
- 年：2016
- 卷：450
- 期：Complete
- 页码：30-38
- 全文大小：884 K
文摘
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FcPPh2 reacts with silver salts yielding diamagnetic, silver-phosphine complexes.
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FcPPh2 reacts with excess AgOTf, yielding a green, paramagnetic, FeIII complex.
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Reaction of [(FcPPh2)3Ag][BF4] with traces of water yields FcP(OBF3)Ph2.
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FcnPPh3–n (n = 1–3), react with S or Se yield ferrocenyl(phenyl)phosphine chalcogenides.
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Reactions between FcPPh2 or FcP(S)Ph2 and bromine yield FcPPh2Br3.