CoFeb>2b>/CoFeb>2b>Ob>4b>/MgO were built for expanding applications of magnetic particles.
Rattle-type photocatalysts were obtained in the absence of template and etchant.
The rattle-type particles exhibited the strong absorption to methylene blue.
The highest degradation efficiency reached 93% for CoFeb>2b>/TiOb>2b>.
CoFeb>2b>/TiOb>2b> can be easily separated due to its high magnetization.
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