Synthesis, electrical and magnetic properties of sodium borosilicate glasses containing Co-ferrites nanoparticles

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• 作者：H.A. Othman^a ; ; M.M. Eltabey^b ; ^c ; Samia.E. Ibrahim^a ; L.M. Sharaf El-Deen^a ; M.M. Elkholy^a
• 关键词：Co-precipitation method ; Cobalt ferrite ; Dielectric constant ; Saturation magnetization ; Coercive field
• 刊名：Physica B: Condensed Matter
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：506
• 期：Complete
• 页码：115-121
• 全文大小：1438 K
• 卷排序：506

文摘

Co-ferrites nanoparticles that have been prepared by the co-precipitation method were added to sodium borosilicate (Na2O–B2O3–SiO2) glass matrix by the solid solution method and they were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) and magnetization measurements. (XRD) revealed the formation of the Co-ferrite magnetic crystalline phase embedded in an amorphous matrix in all the samples. The investigated samples by (TEM) showed the formation of the cobalt ferrite nanoparticles with a spherical shape and highly monodispersed with an average size about 13 nm. IR data revealed that the BO3 and BO4 are the main structural units of these samples network. IR spectra of the investigated samples showed the characteristic vibration bands of Co-ferrite. Composition and frequency dependent dielectric properties of the prepared samples were measured at room temperature in the frequency range 100–100 kHz. The conductivity was found to increase with increasing cobalt ferrite content. The variations of conductivity and dielectric properties with frequency and composition were discussed. Magnetic hysteresis loops were traced at room temperature using VSM and values of saturation magnetization MS and coercive field HC were determined. The obtained results revealed that a ferrimagnetic behavior were observed and as Co-ferrite concentration increases the values of MS and HC increase from 2.84 to 8.79 (emu/g) and from 88.4 to 736.3 Oe, respectively.