New rhenium(III) semiclathrochelates with biorelevant apical substituents: Synthesis, X-ray structure and reactivity
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- 作者：Alexander S. Belova ; Valentin V. Novikova ; Genrikh E. Zelinskiia ; Anna V. Vologzhaninaa ; Oleg A. Varzatskiib ; Boris F. Myasoedovc ; Yan Z. Voloshina ; d ; voloshin@ineos.ac.ru" class="auth_mail" title="E-mail the corresponding author
- 关键词：Clathrochelates ; Rhenium complexes ; Ligand reactivity ; Vector groups ; Radiodiagnostics ; Radiotherapy
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：October 2016
- 年：2016
- 卷：72
- 期：Complete
- 页码：23-29
- 全文大小：791 K
文摘
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Tris-dioximate rhenium(III) semiclathrochelates underwent reduction domino-reactions.
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These ligand-centered reactions gave the reduced diimine-iminoximate derivatives.
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Template condensation on Re3 + ion afforded its formylphenylboron-capped tris-dioximate.
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This semiclathrochelate undergoes a further H+-catalyzed condensation with isoniazid.
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The obtained semiclathrochelate hydrazone contains an apical vector substituent.