Graphene-based materials via benzidine-assisted exfoliation and reduction of graphite oxide and their electrochemical properties

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• 作者：E.C. Vermisoglou^a ; T. Giannakopoulou^a ; G. Romanos^a ; N. Boukos^a ; V. Psycharis^a ; C. Lei^b ; C. Lekakou^b ; D. Petridis^a ; C. Trapalis^a ; ^{c.trapalis@inn.demokritos.gr" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Benzidine ; Reduced graphene oxide ; Pillaring ; Intercalation ; Graphene ; Electrochemical properties
• 刊名：Applied Surface Science
• 出版年：2017
• 出版时间：15 January 2017
• 年：2017
• 卷：392
• 期：Complete
• 页码：244-255
• 全文大小：4054 K

文摘

Benzidine, a compound bearing aromatic rings and terminal amino groups, was employed for the intercalation and simultaneous reduction of graphite oxide (GO). The aromatic diamine can be intercalated into GO as follows: (1) by grafting with the epoxy groups of GO, (2) by hydrogen bonding with the oxygen containing groups of GO. Stacking between benzidine aromatic rings and unoxidized domains of GO may occur through π-π interaction. The role of benzidine is influenced by pH conditions and the weight ratio GO/benzidine. Two weight ratios were tested i.e. 1:2 and 1:3. Under strong alkaline conditions through K₂CO₃ addition (pH ∼10.4–10.6) both intercalation and reduction of GO via amino groups occur, while under strong acidic conditions through HCl addition (pH ∼1.4–2.2) π-π stacking is preferred. When no base or acid is added (pH ∼5.2) and the weight ratio is 1:2, there are indications that reduction and π-π stacking occur, while at a GO/benzidine weight ratio 1:3 intercalation via amino groups and reduction seem to dominate. The aforementioned remarks render benzidine a multifunctional tool towards production of reduced graphene oxide. The effect of pH conditions and the GO/benzidine weight ratio on the quality and the electrochemical properties of the produced graphene-based materials were investigated. Cyclic voltammetry measurements using three-electrode cell and KCl aqueous solution as an electrolyte gave specific capacitance values up to ∼178 F/g. When electric double-layer capacitors (EDLC) were fabricated from these materials, the maximum capacitance in organic electrolyte i.e., tetraethyl ammonium tetrafluoroborate (TEABF₄) in polycarbonate (PC) was ∼29 F/g.