Probing cellulose/polylactic acid interactions in model biocomposite by colloidal force microscopy

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• 作者：Gijo Raj ; Eric Balnois ; Christophe Baley ; Yves Grohens
• 关键词：Cellulose ; Polylactic acid ; Biocomposite ; Adhesion ; AFM
• 刊名：Colloids and Surfaces A: Physicochemical and Engineering Aspects
• 出版年：2009
• 出版时间：5 December 2009
• 年：2009
• 卷：352
• 期：1-3
• 页码：47-55
• 全文大小：1157 K

文摘

Over the last few years, intensive research has been devoted to the exploitation of “green products” based on natural resources for both matrices and as reinforcements in composite systems. The mechanical properties of reinforced biocomposites, such as flax/polylactic acid (PLA), are largely governed by interfacial properties between the two constituents apart from their intrinsic properties. Although many papers indirectly demonstrate the importance of optimising the interface between these two polymers, the exact nature of the interaction between the natural fibre and the polymeric matrix has not been clearly investigated on a fundamental level and is presently a major technological limitation of these materials.

This work presents the first direct study of adhesion forces, by colloidal force microscopy, between smooth PLA films representing the polymer matrix, and a microbead of cellulose that mimic the cellulose material in flax fibres. Normalised adhesion force measurements have shown the importance of capillary forces when experiments were carried out under ambient conditions. Experiments, conducted under dry air, allowed for the deduction of the contribution of pure van der Waals forces, and our results, through the calculation of the Hamaker constant, show that these forces, for the PLA/cellulose/air system, were lower than those obtained for the cellulose/cellulose/air system and hence underlined the importance of optimising the interface among these materials. This study demonstrates the capacity of AFM to probe direct interactions in complex systems by adjusting the nature of the surface and the probe to mimic the materials in contact. Furthermore, the technique can be operated in a variety of environments, consistent with composite making and provides particular opportunity for testing and improving the properties of these new classes of composite materials.