Generation of acidic sites in Al, Ga, In salts of molybdenum and tungsten Keggin-type heteropolyacids. DFT modeling and catalytic tests
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- 作者：R. Tokarz-Sobieraj
- 关键词：Aluminum ; Gallium ; Indium heteropolyacids salts ; DFT calculations ; Ethanol conversion
- 刊名：Catalysis Today
- 出版年：2015
- 出版时间：15 November 2015
- 年：2015
- 卷：257
- 期：part_P1
- 页码：72-79
- 全文大小：2303 K
文摘
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- <p id="par0005">MePMo salts exhibit weak redox properties while MePW is not active in redox reaction.p>
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- <p id="par0010">Both types of salts MePW and MePMo are active in acidic reactions.p>
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- <p id="par0015">Acidic properties change in decreasing order HPW > GaPW > InPW > AlPW >>> HPMo > GaPMo > InPMo > AlPMo.p>
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- <p id="par0020">Theoretical predictions were confirmed by experimental results.p>