Effect of methane on the conversion of HFC-134a in a dielectric barrier discharge non-equilibrium plasma reactor
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- 作者：Sazal K. Kundua ; Eric M. Kennedya ; eric.kennedy@newcastle.edu.au" class="auth_mail" title="E-mail the corresponding author ; John C. Mackiea ; Clovia I. Holdsworthb ; Thomas S. Molloya ; Vaibhav V. Gaikwada ; Bogdan Z. Dlugogorskic
- 关键词：HFC-134a ; Greenhouse gas ; Non-equilibrium plasma ; Dielectric barrier discharge ; Polymer from HFC-134a ; Polymer characterisation
- 刊名：Chemical Engineering Journal
- 出版年：2016
- 出版时间：15 January 2016
- 年：2016
- 卷：284
- 期：Complete
- 页码：412-421
- 全文大小：1111 K
文摘
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Treatment of HFC-134a with methane in a non-equilibrium plasma is investigated.
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The reaction mechanism includes experimental data and quantum chemical analyses.
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The targeted products from the treatment of HFC-134a are fluoropolymers.
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NMR and FTIR spectroscopic analyses reveal that the polymers are random copolymers.