Study on Molecularly Imprinted Sensor Based on Photocurrent Response for Ni-complex

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• 作者：Xiao-Ping WEI ; Shun-Chao LIANG ; Wen-Gang HUANG ; Jian-Ping LI ; ^{likianping@263.net" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Molecularly imprinted sensor ; Photocurrent ; Nickel-1-(2-pyridylazo)-2-naphthol ; Quantum dot ; Nickel ion
• 刊名：Chinese Journal of Analytical Chemistry
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：44
• 期：3
• 页码：348-354
• 全文大小：1068 K

文摘

A novel molecularly imprinted sensor based on photocurrent was fabricated to detect Ni²⁺. CdTe quantum dots (QDs) were selected as photoelectric material and modified on an indium-tin oxide (ITO) electrode, then the nickel-1-(2-pyridylazo)-2-naphthol molecularly imprinted film was formed on the QDs layer by photopolymerization. While 365 nm ultraviolet light was used as the excitation light, an electron-hole pair could be generated by the QDs. The electron receptor ascorbic acid would form a photocurrent under the excitation of the electron as detection signals. Ni²⁺ was determined according to “gate-effect”. The complex was characterized by Fourier transform infrared spectrum and the CdTe QDs were characterized by ultraviolet absorption spectrum and fluorescence emission spectrum. The time for elution and rebinding, as well as the concentration of ascorbic acid, were also optimized. The experimental results indicated that there was a liner relationship between the photocurrent and the concentrations of Ni²⁺ in the range of 5 × 10⁻¹¹ − 5 × 10⁻⁸ M, with a detection limit of 8.31 × 10⁻¹² M. The sensor had good selectivity, and was applied in real water samples analysis.