Hydroformylation of 1-octene in Pickering emulsion constructed by amphiphilic mesoporous silica nanoparticles
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- 作者：Yaopeng Zhaoa ; ypzhao@dicp.ac.cn" class="auth_mail" title="E-mail the corresponding author ; ; Xiaoming Zhanga ; b ; Jayakumar Sanjeevia ; b ; Qihua Yanga ; yangqh@dicp.ac.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Pickering emulsion ; Hydroformylation ; Mesoporous silica nanospheres ; 1-Octene
- 刊名：Journal of Catalysis
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：334
- 期：Complete
- 页码：52-59
- 全文大小：1681 K
文摘
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An O/W Pickering emulsion constructed with SiO2-nanospheres exhibits good catalytic performance in hydroformylation of 1-octene.
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Mesoporous SiO2-nanospheres could not only accelerate the mass transfer but also provide a favorable microenvironment for hydroformylation.
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Grafted cationic groups can efficiently enrich Rh-TPPTS on biphasic interface.