Comparison of “on water” and solventless procedures in the rhodium-catalyzed hydroformylation of diolefins, alkynes, and unsaturated alcohols
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- 作者：W. Alsalahi ; A.M. Trzeciak ; anna.trzeciak@chem.uni.wroc.pl" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydroformylation ; On water ; Rhodium ; Solventless
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：423
- 期：Complete
- 页码：41-48
- 全文大小：593 K
文摘
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Highly efficient hydroformylation was performed under solventless conditions.
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Dialdehydes were formed selectively in “on water” hydroformylation of dienes.
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Linear aldehyde was obtained from phenylacetylene in “on water” conditions.
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Solventless conditions facilitated formation of linear aldehydes from alcohols.