Hydrogenation effect on the hysteresis properties of rapidly quenched Nd-Ho-Fe-Co-B alloys
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文摘
The hydrogenation effect on the hysteresis properties of rapidly quenched (RQ) (Nd0.55Ho0.45)2.7(Fe0.8Co0.2)14B1.2 compound obtained by melt-spinning is studied. A comparative study of RQ alloy and its hydride (Nd0.55Ho0.45)2.7(Fe0.8Co0.2)14B1.2H2.5 has shown that hydrogenation resulted in the increase of magnetization without significant effect on the Curie temperature. In contrast to hydrogen-free alloy having a maximum on the Hc(T) curve, the Hc of the hydrogen-charged compound increased monotonously with decreasing temperature. Among the factors affecting Hc in hydrogenated sample are the increase of the grain size of the crystalline phase and the decrease of both the iron and the rare earth contributions to the magnetocrystalline anisotropy. High-field hysteretic distortions of the magnetization/demagnetization curves of RQ and RQ + hydrogen samples are observed at 4.2 K in fields up to 90 kOe indicating the existence of a magnetic phase with very high local coercivity.

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