Joining of Zirconia and Ti-6A1-4V Using a Ti-based Amorphous Filler
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文摘
Polycrystalline ZrO2-3 mol. % Y2O3 was brazed to Ti-6AI-4V by using a Ti47Zr28Cu4lNi11(at. % ) amorphous ribbon at 1123?273 K in a high vacuum. The influences of brazing temperature on the microstructure and shear strength of the joints were investigated. The interfacial microstructures can be described as ZrO2/TiO+TiO2+Cu2Ti4O+Ni2Ti4O/¦Á-Ti+(Ti,Zr)2(Cu,Ni) eutectic/acicular Widmanst?ten structure/Ti-6AI-4V alloy. With the increase in the brazing temperature, the thickness of the TiO+TiO2+Cu2Ti4 O+Ni2Ti4 O layer reduced, the content of the ¦Á-Ti+(Ti,Zr)2(Cu,Ni) eutectic phase decreased, while that of the coarse ¦Á-Ti phase gradually increased. The shear strength of the joints did not show a close relationship with the thickness of the TiO+TiO2+Cu2Ti4O+Ni2Ti4O layer. However, when the coarse (Ti,Zr)2(Cu,Ni) phase was non-uniformly distributed in the ¦Á-Ti phase, or when ¦Á-Ti solely situated at the center of the joint, forming a coarse block or even connecting into a continuous strip, the shear strength greatly decreased.

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