The production of carbon nanotube/epoxy composites with a very high dielectric constant and low dielectric loss by microwave curing
详细信息 查看全文
文摘
Multiwalled carbon nanotube (MWCNT)/epoxy (EP) composites were developed using microwave curing (m-MWCNT/EP). They have a very high dielectric constant and low dielectric loss. For comparison, composites based on the same components were also prepared by thermal curing (t-MWCNT/EP). Results show that the two types of composites have greatly different dielectric properties. With the same content of MWCNTs, m-MWCNT/EP composites show a much higher dielectric constant and lower dielectric loss than t-MWCNT/EP composites. Specifically, the dielectric constant and loss at 100 Hz of m-MWCNT/EP composite with 0.04 vol % MWCNTs are about 2.5 and 0.05 times the corresponding value of t-MWCNT/EP composites, respectively, because of their different structures. Compared with t-MWCNT/EP composites, the nanotubes in m-MWCNT/EP composites not only have a better dispersion in the matrix, but also align in a direction. An equivalent circuit model was set up to evaluate the influence of dispersion and spatial distribution of MWCNTs on the dielectric properties. It shows that it is possible to control the dispersion and spatial distribution of carbon nanotubes using a different curing technique to obtain high performance composites with unexpected dielectric properties, especially those with very high dielectric constant and low dielectric loss.