Anthracene and pyrene photolysis kinetics in aqueous, organic, and mixed aqueous-organic phases
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- 作者：Jarod N. Grossman ; Adam P. Stern ; Makena L. Kirich ; Tara F. Kahan ; tfkahan@syr.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Photochemistry ; Sea surface microlayer ; Particulate matter ; Core&ndash ; shell ; Dissolved organic matter
- 刊名：Atmospheric Environment
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：128
- 期：Complete
- 页码：158-164
- 全文大小：520 K
文摘
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We have investigated the effects of organic matter on PAH photolysis kinetics.
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PAH photolysis kinetics in aqueous and organic phases depend primarily on polarity.
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Kinetics in homogeneous aerosols can be predicted by organic and aqueous fractions.
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Kinetics in phase-separated aqueous-organic aerosols are complex.
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Our results will enable more accurate predictions of PAH photolysis kinetics.