Thermal kinetics and scissoring mechanism of LDPE/rGO nanocomposites were studied. First order kinetics characteristics of nanocomposites was calculated according to Kissinger and Flynn-Wall Ozawa model. rGO can effectively increase the thermal stability of the nanocomposites with highest correlation coefficient in 3 wt% rGO content. Useful gaseous compound, pravastatin was detected during the scissoring mechanism through TGA-GC/MS.