The in-situ transformation of M7C3 to M23C6 is first observed directly in cobalt-base superalloys. M23C6 carbide nucleates at the M7C3/matrix interface due to the coherent relationship between M23C6 carbide and the matrix. The primary MC degenerates and releases of a large amount of Ti and W at elevated temperature. The primary MC decomposes into M6C at 1140 °C and dissolves partially into the matrix above 1140 °C.