A new heterobimetallic manganese-rhodium carbonyl complex derived from partially alkylated s-indacene
详细信息 查看全文
- 作者：Cé ; sar Morales-Verdejo<sup>asup><sup> ; sup><sup>camoralv@uc.clsup> ; Luciano Oehninger<sup>bsup><sup> ; sup><sup>dsup> ; Ivá ; n Martí ; nez-Dí ; az<sup>bsup> ; Desmond Mac-Leod Carey<sup>csup> ; Ramiro Arratia-Pé ; rez<sup>csup> ; Ivonne Chá ; vez<sup>bsup> ; Juan Manuel Manrí ; quez<sup>bsup>
- 关键词：Organometallic ; Heterobimetallic complexes ; DFT
- 刊名：Inorganica Chimica Acta
- 出版年：2013
- 出版时间：1 January, 2013
- 年：2013
- 卷：394
- 期：Complete
- 页码：132-139
- 全文大小：910 K
文摘
This work describes the synthesis and characterization by means of <sup>1sup>H, <sup>13sup>C NMR and FT-IR spectroscopies of new heterobinuclear carbonylated complex derived from partially alkylated s-indacene. The heterobimetallic complex [(CO)<sub>3sub>Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(COD)] 1 was synthesized from the monometallic specie [(CO)<sub>3sub>Mn(2,6-diethyl-4,8-dimethyl-1-hydroindacenide)] and [Rh(¦Ì-Cl)(COD)]<sub>2sub>. Secondly, its respective carbonylated complex [(CO)<sub>3sub>Mn(2,6-diethyl-4,8-dimethyl-s-indaceneiide)Rh(CO)<sub>2sub>] 2 was obtained by under an atmosphere of carbon monoxide in hexanes. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.