[Hg(9-methyl-1-deazapurine)₂](NO₃)₂??H₂O: a complex with a distorted hexagonal bipyramidal metal ion coordination sphere

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• 作者：M??ller ; Jens ; Polonius ; Fabian-Alexander ; Roitzsch ; Michael
• 关键词：Bioinorganic chemistry ; Deazapurine ; Metal-mediated base pair ; Mercury
• 刊名：Inorganica Chimica Acta
• 出版年：2005
• 出版时间：March 1, 2005
• 年：2005
• 卷：358
• 期：4
• 页码：1225-1230
• 全文大小：180 K

文摘

Reaction of 9-methyl-1-deazapurine (9-MeDP) with Hg(CF₃COO)₂ in the presence of NaNO₃ yields the title compound [Hg(9-MeDP)₂](NO₃)₂??H₂O with the two 9-MeDP ligands bound to the metal ion via their N7 positions. The X-ray structure is reported: monoclinic, P2₁/c (no. 14), a