Role of surfactants on metal mediated cerium(IV) oxidation of valeraldehyde at room temperature and pressure
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- 作者：Aniruddha Ghosh ; Pintu Sar ; Susanta Malik ; Bidyut Saha ; b_saha31@rediffmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Valeraldehyde ; Ce(IV) ; Ir(III) ; Valeric acid ; CTAB
- 刊名：Journal of Molecular Liquids
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：211
- 期：Complete
- 页码：48-62
- 全文大小：4293 K
文摘
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Valeric acid is used in variety of industrial target compounds and pharmaceuticals.
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Water has been used as green solvent in place of hazardous organic solvents.
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Non-toxic Ce(IV) has been selected as the oxidizing source in comparison to Cr(VI), Fe(VI), and Pb(IV).
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The incorporation of active species Ce(SO4)2 + and valeraldehyde into the stern layer of micelles is reported the first time.
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Ru(III) in association with CTAB micelle exhibited a dramatic ~ 330 fold rate enhancement.