Synthesis and electrochemical characterization of oligothiophenes with 1,2,4-triazine and 5,5′-bi-1,2,4-triazine as strong electron acceptor units
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- 作者：Danuta Branowskaa ; dankab@uph.edu.pl" class="auth_mail" title="E-mail the corresponding author ; danuta.branowska@uph.edu.pl" class="auth_mail" title="E-mail the corresponding author ; Ewa Olendera ; Waldemar Wysockia ; Zbigniew Karczmarzyka ; Ilona Bancerza ; Przemyslaw Ledwonb ; przemyslaw.ledwon@polsl.pl" class="auth_mail" title="E-mail the corresponding author ; Mieczyslaw Lapkowskib ; c ; 1 ; Barbara Mirosławd ; Zofia Urbańczyk-Lipkowskae ; Przemysław Kalickie
- 关键词：Stille reaction ; X-ray analysis ; Spectroelectrochemistry ; 1 ; 2 ; 4-triazine ; Electron acceptor ; Radical anion ; DFT calculations
- 刊名：Electrochimica Acta
- 出版年：2016
- 出版时间：1 October 2016
- 年：2016
- 卷：214
- 期：Complete
- 页码：19-30
- 全文大小：2010 K
文摘
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1,2,4-triazine and 5,5′-bi-1,2,4-triazine oligothiophene derivatives were synthesized.
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Electrochemically generated anion-radicals were characterized.
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5,5′-bi-1,2,4-triazine unit presents strong electron-acceptor properties.