Heteroaggregation between GO and KGa-1b is not favorable under normal conditions. High ionic strength and low pH values enhance the attachment of GO onto KGa-1b. The attachment of GO onto KGa-1b is exothermic and not spontaneous. GO −(KGa-1b) formation is attributed to surface charge changes of KGa-1b colloids. The CCC for the heteroaggregation between GO and KGa-1b is 152 mM NaCl.