Synthesis, crystal structures and catalytic activity of Cu(II) and Mn(III) Schiff base complexes: Influence of additives on the oxidation catalysis of cyclohexane and 1-phenylehanol
Oxidation of cyclohexane with H2O2 catalysed by copper and manganese complexes. Pronounced promoting effect of pyridine. Direct GCMS observation of cyclohexyl hydroperoxide as a main reaction product. The formation of chlorocyclohexane in the presence of HCl promoter. Solvent-free oxidation of phenylethanol with t-BuOOH.