Ag3PO4/TiO2@MoS2 with heterostructure and low bandgap was successfully synthesized. Ag3PO4/TiO2@MoS2 showed high photocatalytic activity and antiphotocorrosion ability. Ag3PO4/TiO2@MoS2 greatly enhanced the separation efficiency of electron-hole pairs. Possible photocatalytic degradation mechanism and pathway were illustrated. Ag3PO4/MoS2@TiO2 is a promising photocatalyst for degradation of organic pollutants.