Synthesis, characterisation and behaviour of Co/hydroxyapatite catalysts in the oxidation of 1,2-dichloroethane
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- 作者：Zouhair Boukha ; zouhair.boukha@ehu.eus" class="auth_mail" title="E-mail the corresponding author ; zouhair.boukha@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; Jonatan Gonzá ; lez-Prior ; Beatriz de Rivas ; Juan R. Gonzá ; lez-Velasco ; Rubé ; n Ló ; pez-Fonseca ; José ; I. Gutié ; rrez-Ortiz
- 关键词：Hydroxyapatite ; Ion-exchanged Co2+ ; Co3O4 ; Surface chemistry ; DCE total oxidation
- 刊名：Applied Catalysis B: Environmental
- 出版年：2016
- 出版时间：5 August 2016
- 年：2016
- 卷：190
- 期：Complete
- 页码：125-136
- 全文大小：2296 K
文摘
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Series of cobalt supported on hydroxyapatite catalysts are synthesised and characterised.
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Three types of cobalt species are detected in the prepared catalysts.
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The Co catalysts have been successfully tested in the oxidation of 1,2-dichloroethane.
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The Co(x)/hydroxyapatite catalysts achieve higher activity compared to bulk Co3O4.
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The distribution of Co species plays a decisive role in the activity and selectivity.