Coordination chemistry of non-oxido, oxido and dioxidovanadium(IV/V) complexes with azine fragment ligands

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• 作者：Manas Sutradhar ; ^{manaschem@yahoo.co.in" class="auth_mail} ; ^{manaschem@gmail.com" class="auth_mail} ; Armando J.L. Pombeiro ; ^{pombeiro@tecnico.ulisboa.pt" class="auth_mail}
• 关键词：Non-oxidovanadium(IV) complexes ; Oxidovanadium(IV) complexes ; Oxidovanadium(V) complexes ; Dioxidovanadium(V) complexes ; Mixed valence complexes ; Heterometallic complexes
• 刊名：Coordination Chemistry Reviews
• 出版年：April, 2014
• 年：2014
• 卷：265
• 期：Complete
• 页码：89-124
• 全文大小：3980 K

文摘

The role of azine fragment ligands for the development of the coordination chemistry of vanadium(IV/V) complexes is reviewed. A wide range of complexes with different (N, O), (N, S) and (O, N, S) donor ligands having non-oxido, oxido and dioxidovanadium centers is illustrated. Methods of syntheses, coordination properties and stabilizing factors for the particular form (non-oxido/oxido/dioxido), reaction conditions, donor properties of the ligands, effect of secondary ligands and other effects are discussed. The review also includes heterometallic and mixed-valence complexes. Important properties, such as DNA binding, antibacterial and anti-amoebal activities, functional models of vanadium-dependent haloperoxidases (VHPOs) and catalytic potential toward peroxidative oxidation of hydrocarbons, of these vanadium complexes are also discussed.