Synthesis of acrylates from olefins and CO₂ using sodium alkoxides as bases

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• 作者：Simone Manzini^a ; Nú ; ria Huguet^b ; Oliver Trapp^a ; ^c ; Rocco A. Paciello^b ; Thomas Schaub^a ; ^b ; ^{thomas.schaub@basf.com}
• 关键词：Homogeneous catalysis ; CO2 activation ; Process development ; Palladium catalysis ; Sodium acrylate synthesis
• 刊名：Catalysis Today
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：281
• 期：part_P2
• 页码：379-386
• 全文大小：1378 K
• 卷排序：281

文摘

NaOtBu could be identified to be a suitable base for the carboxylation of CO2. Simple and efficient access to sodiumacrylate based on CO2. Recycling concept for the palladium catalyst developed. Applied to hitherto non-reactive olefins in this carboxylation.