The results obtained show that, application of the investigated hydrogels positively affects bio-chemical properties of the soil. These effects are assembled in the following: (a) slightly decreasing soil pH, (b) increasing cation exchange capacity (CEC) of the soil indicating improvement in activating chemical reactions in the soil, (c) increasing organic matter (OM), organic carbon, total nitrogen percent in the soil. Because the increase in organic nitrogen surpassed that in organic carbon, a narrower CN ratio of treated soils was obtained. This indicated the mineralization of nitrogen compounds and hence the possibility to save and provide available forms of N to growing plants, (d) increasing available N, P and K in treated soil, and (e) improving biological activity of the soil expressed as total count of bacteria and counts of Azotobacter sp., phosphate dissolving bacteria (PDB), fungi and actinomycetes/g soil as well as the activity of both dehydrogenase and phosphatase.