Palladium-catalyzed formation of secondary and tertiary amines from aryl dihalides with air-stable ferrocenyl tri- and diphosphines: Synthesis and X-ray structure of efficient catalysts beyond [PdCl2(DPPF)]
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- 作者：Sophal Moma ; Mé ; lanie Platona ; Hé ; lè ; ne Catteya ; Howard J. Spencerb ; Paul J. Lowb ; c ; paul.low@uwa.edu.au" class="auth_mail ; Jean-Cyrille Hiersoa ; d ; jean-cyrille.hierso@u-bourgogne.fr" class="auth_mail
- 关键词：Palladium ; Ferrocenylphosphine ; Aniline ; Dihaloarenes ; C&ndash ; N coupling ; X-ray structure
- 刊名：Catalysis Communications
- 出版年：5 June 2014
- 年：2014
- 卷：51
- 期：Complete
- 页码：10-14
- 全文大小：724 K
文摘
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Pd triphosphine catalyst for C–N bond formation of functionalized secondary amines
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Pd diphosphine catalyst for C–N bond formation of functionalized tertiary amines
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Convenient procedure for selective monoamination of aryl dihalides at 1 mol% Pd
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Air-stable and commercial (or easily made) ferrocenylphosphines ligands
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X-ray of a Pd(II) pre-catalyst for a new ferrocenyldiphosphine ligand