The simultaneous determination of metal ions based on SPES and UV-Visible couple with multivariate calibration spectroscopy was proposed.
The spectra of the analytes on the membranes were measured directly without eluting.
The method was used to quantify trace cobalt (II) and zinc (II) in three real samples.
The proposed method is simple, sensitive and selective.
The applicability of the method can be extended to other analytes.