文摘
The synthesis and properties of glass-forming diphenylamino-substituted derivatives of 9-phenylcarbazole with methoxy groups in the different position of diphenylamino moieties are reported. A comparative study on their thermal, optical, photoelectrical and electrochemical properties is presented. The synthesized compounds exhibit high thermal stability with 5 % weight loss temperatures ranging from 344 to 475 ¡ãC. The derivatives absorb electromagnetic irradiation in the range of 225-425 nm with the band gaps of 2.94-3.08 eV. The ionization energies of the synthesized compounds range from 5.04 to 5.56 eV. The lowest ionization energies and band gaps are observed for compounds containing para methoxy-substituted phenyl rings of diphenylamino moieties and for disubstituted carbazole derivatives. Charge-transporting properties of the selected compounds were tested by time-of-flight technique. Hole drift mobilities in the amorphous layers of the materials reach 10?3 cm2/V s at high electric fields. The derivatives were tested as hole transport materials in solid-state dye sensitized solar cells and showed conversion efficiency up to 0.54 % .