Assembly of a 3D chiral Cu(I) metal-organic framework based on 4,5-dicyanoimidazole: CD spectrum, luminescence and selective gas adsorption
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- 作者：Tuo-Ping Hu ; hutuopingsx@126.com" class="auth_mail" title="E-mail the corresponding author ; Xiao-Xiao Wang ; Bao-Hua Zheng ; Xiao-Qing Wang ; Xue-Na Hao ; Jian-Feng Liu
- 关键词：Metal&ndash ; organic framework ; Chiral ; Gas adsorption ; Photoluminescent
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：68
- 期：Complete
- 页码：17-20
- 全文大小：757 K
文摘
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One novel chiral Cu(I) metal–organic framwork has been obtained based on nitrobenzene.
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The 3D metal–organic framework can be regarded as a PtS net with the vertex symbol of {42.84}.
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The gas adsorption/desorption experiments of complex 1 have been measured at 77 K.