Luminescent cadmium coordination polymers synthesized from bis(4-pyridylmethyl)piperazine and isophthalic acid derivatives

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• 作者：Brian L. Pickwick ; Amy L. Pochodylo ; Robert L. LaDuca ; ^{laduca@msu.edu}
• 关键词：Crystal structure ; Coordination polymer ; Luminescence ; Cadmium ; Isophthalate
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 March 2017
• 年：2017
• 卷：458
• 期：Complete
• 页码：146-162
• 全文大小：6191 K
• 卷排序：458

文摘

Cadmium 5-substituted isophthalate coordination polymers. Use of long-spanning bis(4-pyridylmethyl)piperazine (4-bpmp) coligand. 1D, 2D, and 3D coordination polymers depending on substituent. 2D + 2D → 3D or 1D + 1D → 3D interpenetration in two cases. Violet, blue, or green luminescence depending on substituent.