Extractive complexation of lanthanides and Am(III) by 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone in ionic liquid: Solvent extraction and spectroscopic studies
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- 作者：Rajesh B. Gujar ; Seraj A. Ansari ; Arijit Sengupta ; Mallekav S. Murali msmurali@barc.gov.in" class="auth_mail" title="E-mail the corresponding author ; Prasanta K. Mohapatra ; mpatra@barc.gov.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Lanthanides ; Extraction ; Complexation ; Ionic liquid ; Pyrazolone
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：73
- 期：Complete
- 页码：72-76
- 全文大小：396 K
文摘
- 5">
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5">Extraction of Am3 +, La3 +, Eu3 + and Lu3 + was studies with HPMBP in RTIL.
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10">Species with RTIL were different than that obtained with molecular solvents.
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15">Cationic species like M(HL)L2+ were extracted.
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Luminescence spectroscopy suggested presence of inner-sphere water.
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5">Stability constants of Nd3 + - HPMBP were determined for the first time.